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The computer controlled temperature cycle from room temperature to -300°F and back occurs at roughly one degree per minute so as to minimize new stresses in the parts. Rapid temperature change, particularly when cooling, is often the cause of harmful residual stresses. By using this type of curve, thick parts and those with a wide variety of shapes can be processed easily. The “soak” at -300°F for over 20 hours causes some interesting things to happen,
metallurgically, which we will attempt to describe.
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The most dramatic results of this process is with hardened steels. This applies to through or case hardened alloy, tool, carbon and heat treatable stainless steels.
Besides the welcome elimination of harmful residual
stress, there are two primary reasons that steels hardened conventionally can be greatly improved with deep cryogenic
processing.
1. Without going into the technical aspects of hardening steels, it is important to note that the transformation of steel heated to
solution, which is called austenite, to the hard structure known as martensite, occurs by decreasing its temperature at a controlled rate. Unfortunately at the normal room temperature floor there is often an incomplete transformation to the desirable
martensite. Much of the matrix may be unconverted, residual austenite. The deep cryogenic process allows this transformation to continue, to the extent where hardness increases of over 5 points on the Rockwell C scale may be noticed. A follow-on tempering step at 300-800° is used to eliminate brittleness, much as in the original hardening operation.
2. Perhaps more importantly is the type of new structures that are formed. New, small carbides, named
n-carbides, are formed at extremely low temperature without an increase in volume. Although the explanation for this molecular movement is beyond the scope of this article, it is thought to occur because electrons are slowed down when chilled. Electrical energy can keep atoms apart. When this energy is reduced they are free to move and combine into new molecules. Over time the new
n-carbides become evenly distributed in the matrix, filling in the gaps and making it less porous. This densification
is the primary reason why cryogenically treated steels become so resistant to abrasion.
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Imagine that steel is porous, with “peaks and valleys” at the wear surface. Under sliding friction, for example, metal-to-metal contact will break off the “peaks.” This particle may then gouge one or the other surface before it goes away, one of the reasons we use lubricants or coolants.
A “CryoTuned” surface will exhibit a more dense matrix with much smaller “peaks and valleys.” This supportive structure resists the degradation of the wear surface and lasts much longer.
Similarly a ground cutting edge on a cryogenically treated tool will be sharper and less jagged than an untreated tool. The microscopic “teeth,” being smaller, cause a finer wear pattern as they break off.
For this reason, cutting tools that are re-sharpened require up to 30% less stock removal to restore edge geometry! This factor alone will contribute to increased tool life. |